By Jacob Bunge 

Farmer-owned cooperative CHS Inc. struck a multibillion-dollar deal with fertilizer maker CF Industries Holdings Inc. that links one of the world's top producers of nitrogen fertilizer with the biggest U.S. wholesaler of crop nutrients.

In a deal that extends a spate of tie-ups in the fertilizer sector, CHS will invest $2.8 billion in a CF subsidiary in return for the right to buy a slice of its production capacity at market prices.

CHS, based in suburban St. Paul, Minn., will pursue the deal with CF instead of moving ahead with plans to build its own nitrogen plant, a long-range plan that had grown costlier and more risky since CHS first announced the project last year, CHS Chief Executive Carl Casale said.

"This lets [each company] focus on what we do well," Mr. Casale said in an interview. For CHS, the deal "will free us up to look at other opportunities."

Shares of CF Industries were 8% higher at $61.55 in afternoon trading Wednesday.

CHS is the largest U.S. farmer cooperative, operating a network of grain elevators, retail stores and fuel operations across the Midwest. The company generated $42.7 billion in sales last year and bills itself as the largest U.S. fertilizer wholesaler.

CF's tie-up with CHS is the latest in a series of planned deals that would reshape the global market for crop nutrients after several years of bumper crops have pushed commodity prices lower and crimped farmers' income, forcing them to scrutinize spending on seeds, sprays and fertilizer.

CF, based in Deerfield, Ill., last week unveiled plans to buy assets of Netherlands-based fertilizer producer OCI NV in an $8 billion deal that would create the largest global provider of nitrogen fertilizer, and shift the combined company's corporate base to the U.K. The deal includes the assumption of $2 billion of debt.

Separately, German salt and fertilizer company K+S AG has rebuffed unsolicited takeover approaches from Canada's Potash Corp of Saskatchewan Inc. that valued K+S at about $8.63 billion.

CHS's deal with CF will more closely link the fertilizer company with a client that regularly ranks among CF's top three customers, according to CF Chief Executive Tony Will.

"CHS is a huge player in North America," Mr. Will said on a conference call Wednesday. "Our business with them has fluctuated up and down but they've always been a significant customer."

The move could also help CF protect profit margins for the company's fertilizer by preventing the entry of a significant new plant hooked up to a major fertilizer buyer, according to Joel Jackson, an analyst with BMO Capital Markets.

As part of Wednesday's deal, CHS will be entitled to semiannual profit distributions. It will also be able to buy up to 1.7 million tons of urea and UAN, a solution of urea and ammonium, at market price each year--8.9% of CF's production capacity.

CHS's Mr. Casale said his company approached CF about the arrangement as CHS faced mounting challenges to its own plan to build a nitrogen plant in North Dakota, including difficulties with the water supply and "significant cost escalations." While the investment ranks as the largest in the cooperative's history, Mr. Casale said, it could save about $500 million in construction costs. Earnings from fertilizer sales under the new arrangement, expected to begin next year, could become CHS's second-largest source of profits, he said.

Mr. Casale said the deal gives CHS more financial firepower and frees up its managers to focus on other ways to expand its business, as the company invests in crop processing, ethanol plants and port facilities to build out its grain-trading capabilities.

Angela Chen contributed to this article.

Write to Jacob Bunge at jacob.bunge@wsj.com

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