By Angela Chen 

Farmer-owned cooperative CHS Inc. will invest $2.8 billion in a subsidiary of fertilizer maker CF Industries Holdings Inc., in return for the right to buy a slice of CF's production capacity at market prices.

CHS will be entitled to semiannual profit distributions. It will also be able to buy up to 1.7 million tons of urea and UAN, a solution of urea and ammonium, at market price each year--8.9% of CF's total production capacity.

CF Industries operates nitrogen-manufacturing complexes in the central U.S. and Canada, and distributes plant nutrients through a system of terminals, warehouses and associated transportation equipment located primarily in the Midwestern U.S.

The subsidiary, CF Nitrogen, owns three production facilities in the U.S. It will continue to operate all the facilities. Pending successful expansion, the facilities will have total production of 18.9 million product tons, not including the new capacity from an earlier deal.

"Entering nitrogen fertilizer manufacturing through the purchase of a minority ownership in CF Nitrogen is the single largest investment in CHS history," said CHS Chief Executive Carl Casale.

Earlier in August, CF agreed to buy parts of a Dutch competitor for about $8 billion and shift its headquarters to the U.K., creating a global nitrogen-fertilizer powerhouse with a significantly lower tax bill.

The transaction is expected to close either Feb. 1 or earlier by mutual consent.

Shares of CF have increased about 5% this year through Tuesday's close.

Write to Angela Chen at angela.chen@wsj.com

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