By Ben Fox Rubin 

Express Scripts Holding Co. named Wal-Mart Stores Inc. executive Cathy Smith as its new chief financial officer, effective Feb. 10.

Ms. Smith has been executive vice president of strategy and chief financial officer for Walmart International since 2010.

Her departure comes after Walmart International CEO Doug McMillon in November was named Wal-Mart's chief executive. Walmart International has more than 6,300 stores and more than 823,000 associates in 26 countries outside the U.S.

Before joining the big-box retailer, Ms. Smith was executive vice president and finance chief for GameStop Corp., and previously held financial roles in companies focused on aerospace and defense, homebuilding and industrial tool manufacturing.

Express Scripts, a St. Louis-based company, manages drug-benefit programs for health plans and corporate customers. It acquired Medco Health Solutions in April 2012, creating the largest pharmacy-benefit manager, or PBM.

Write to Ben Fox Rubin at ben.rubin@wsj.com

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